Angewandte
Communications
Chemie
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catalyzed hydroboration by using a well-defined manganese
complex. The results shall provide significant implication for
future catalyst design based upon earth-abundant elements, in
particular the underexplored manganese.
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We are grateful to donors of the American Chemical Society
Petroleum Research Fund for partial support of this work
(54247-UNI3). We also acknowledge the support from CUNY
Collaborative Research Incentive Program, the PSC-CUNY
award (69069-0047) and a “Seed Grant” support from the
Office for the Advancement of Research and the Program for
Research Initiatives for Science Majors (PRISM) at John Jay
College, CUNY. Partial support from National Science
Foundation (NSF, CHE-1464543) and NSF (0840444) for
Dual source X-ray diffractometer is gratefully acknowledged.
Hunter MS and NMR facilities are also acknowledged.
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Keywords: alkenes · carbonyl compounds · hydroboration ·
manganese catalysis · Markovnikov selectivity
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Received: August 4, 2016
Revised: September 7, 2016
Published online: && &&, &&&&
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ꢀ 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
Angew. Chem. Int. Ed. 2016, 55, 1 – 5
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