Tetrahedron p. 3471 - 3480 (1984)
Update date:2022-08-06
Topics: Synthesis Stereoisomers Pheromone Energetically possible 5>decane
Mori, Kenji
Ikunaka, Masaya
All of the four energetically possible stereoisomers<(2R,5R,7R)-, (2R,5S,7S)-, (2S,5R,7R)- and (2S,5S,7S)- isomers> of 7-ethyl-2-methyl-1,6-dioxaspiro<4.5>decane were synthesized starting from ethyl (S)-lactate and dimethyl (S)-malate or methyl (R)-β-hydroxy-valerate employing dianion alkylation as the key-step.
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