B.P. Baranwal et al. / Spectrochimica Acta Part A 84 (2011) 125–129
129
Table 4
character and possess Ti–O–C linkage too, which is mainly required
for their catalytic property. They have high hydrolytic stability and
coordination number of titanium is assigned to seven or eight in
the complexes.
Powder XRD structural data for complex 1.
Parameters
1
Empirical formula
Crystal system
Bravice lattice
Space group
TiC28H43O7Cl
Triclinic
Primitive
P1
Acknowledgements
˚
a (A)
8.69
3.50
2.21
5.05
12.71
20.49
Authors are thankful to the CSIR [no. 01(2293)/09/EMR-II] and
[no. 09/057/(0200)/2010/EMR-I], and UGC [F. no. 37-132/2009
(SR)], New Delhi for financial support. They also thank CDRI, Luc-
know for spectral and microanalysis.
˚
b (A)
˚
c (A)
˛ (◦)
ˇ (◦)
ꢆ (◦)
Limiting indices
References
˚
h (A)
8.69
3.50
2.21
337
˚
k (A)
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(ˇ cos ꢀ)
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4. Conclusions
Designing of a novel type of mononuclear, non-oxo, mixed-
ligand complexes of titanium(IV) containing different ligands
around the metal has been made which have spherical shaped par-
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