A Facile Synthesis of Bicycloalkan-1-ols. Evidence for Organosamarium Intermediates in the Samarium(II) Iodide Promoted Intramolecular Barbier-Type Reaction

DOI: 10.1021/jo00013a008

Source and publish data:

Journal of Organic Chemistry p. 4112 - 4120 (1991)

Update date:2022-09-26

Topics: Facile Synthesis Samarium(II) iodide Organosamarium Intermediates Intramolecular Barbier-Type Reaction

Authors:

Molander, Gary A.

McKie, Jeffrey A.

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Article abstract of DOI:10.1021/jo00013a008

Samarium(II) iodide (SmI2) has been successfully employed as a reductive coupling agent for the intramolecular Barbier-type synthesis of bicycloalkan-1-ols.Thus, a variety of 3-(ω-iodoalkyl)cycloalkanones, upon treatment with SmI2 and a catalytic q

Full text of DOI:10.1021/jo00013a008

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Article Doi

A Facile Synthesis of Bicycloalkan-1-ols. Evidence for Organosamarium Intermediates in the Samarium(II) Iodide Promoted Intramolecular Barbier-Type Reaction

DOI: 10.1021/jo00013a008

Source and publish data:

Authors:

Article abstract of DOI:10.1021/jo00013a008

Full text of DOI:10.1021/jo00013a008

Products guided by the article

R&D Labs maybe for 134655-22-4

Relevant to this article

New sulfonyl-containing materials for nonlinear optics: Semiempirical calculations, synthesis, and properties

Synthesis of pro-prodrugs l-lysine based for 5-aminosalicylic acid and 6-mercaptopurine colon specific release

Cobalt-mediated [2+2+2] cycloadditions of pyrimidine derivatives to alkynes

Electrochemical carboxylation of cinnamate esters in MeCN

Radical Mediated Intramolecular <3-Atom + 2-Atom> Addition and the Synthesis of (+/-)-Rocaglamide: Model Studies

Conformational Study of N-Nitroso-2,6-diphenylpiperidines and N-Nitroso-2,6-diphenylpiperidin-4-ones by Molecular Mechanics Calculations, X-ray Crystallography, and 1H and 13C NMR Spectroscopy