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[15] Despite the fact that Ni-catalyzed direct coupling of alcohol and
alkyne seems like a more elegant alternative for the synthesis of
allylic alcohols (see ref 4a), the current method not only represented
a new type of coupling reaction, but it also displayed higher
reactivity than the alcohol’s coupling. For example, higher yields for
wider scope of substrates can be observed. In addition,
aryl-substituted alkynes that did not work in the reported
Ni-catalyzed reaction were also well compatible. The use of common
reducing agents greatly facilitated the improvement of the reaction
and as well as the development of analogous reactions because
modifying the common reducing agent is easier than tuning each
substrate.
[16] Two 5-membered nickellacyles formed a Ni-Ni species was also
possible, please see: Zhang, G.; Xie, Y.; Wang, Z.; Liu, Y.; Huang, H.
Chem. Commun. 2015, 51, 1850.
(The following will be filled in by the editorial staff)
Manuscript received: XXXX, 2019
Manuscript revised: XXXX, 2019
Manuscript accepted: XXXX, 2019
Accepted manuscript online: XXXX, 2019
Version of record online: XXXX, 2019
[11] Bausch, C. C.; Patman, R. L.; Breit, B.; Krische, M. J. Angew. Chem. Int.
4
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Chin. J. Chem. 2019, 37, XXX-XXX
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