Journal of Carbohydrate Chemistry p. 559 - 574 (2011)
Update date:2022-08-03
Topics:
Decroocq, Camille
Laparra, Laura Mamani
Rodriguez-Lucena, David
Compain, Philippe
Azide-armed α-1-C-alkyl-imino-d-xylitol derivatives have been efficiently prepared by way of olefin cross-metathesis in eight to nine steps and in an overall yield of 19% to 26% from 2,3,4-tri-O-benzyl-d-xylopyranose. Optimization of cleavage conditions of N-NAP-protected tertiary amines using DDQ in CH2Cl2-H2O (18:1) is also reported. The iminosugars synthesized will be used as key building blocks in the synthesis of multivalent iminosugars of biological interest by way of Cu(I)-catalyzed azide-alkyne cycloaddition reaction.
View MoreContact:+86 512 6287 2180
Address:398 Ruoshui Road, Suzhou Industrial Park, Suzhou, Jiangsu, P. R. China
Hebei Think-Do Environment Co., Ltd
website:http://www.thinkdo-environment.com
Contact:0311-86510809
Address:No 6, Shilian Middle Street, Circular Chemical Industry Park
Contact:+86-570-4336358
Address:No.87 Building,Tianqian,Sidu Town
website:http://www.eastarchem.com/
Contact:1-800-898-2436
Address:1215 K Street, STE 1700
SPRING CHEMICAL INDUSTRY CO.,LTD
Contact:86-187-66672125
Address:linchi industry park.zouping
Doi:10.1016/0022-328X(91)86132-A
(1991)Doi:10.1016/0223-5234(91)90021-E
(1991)Doi:10.1016/S0040-4020(01)86441-3
(1991)Doi:10.1039/c2cc16758a
(2012)Doi:10.1021/om200999n
(2012)Doi:10.1007/s10870-011-0165-9
(2011)