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2162;
(529.58): C, 54.43; H, 5.71, N, 10.58; S, 12.11. Found: C, 54.30; H,
5.67, N, 10.69; S, 12.16%.
4.3.4. Bis(N,N-dibenzyl-N0-benzoylthioureato)cobalt(II) (2d)
Yield: 84%. Pink neon solid; mp: 194–196 °C. IR (KBr):
m = 3060,
3028, 1582, 1514, 1409, 1072 cmꢀ1. MS-EI m/z (%): 778 (100), 448
(26), 359 (41), 196 (30), 105 (1). Elemental analysis Anal. Calc. for
C44H38CoN4O2S2 (777.18): C, 67.94; H, 4.92; N, 7.20; S, 8.24. Found:
C, 67.87; H, 4.89; N, 7.30; S, 8.27%.
4.3.5. Bis(N,N-diphenyl-N0-furoylthioureato)copper(II) (2e)
Yield: 73%. Lime green solid; mp: 300–302 °C. IR (KBr):
m
= 3046, 3012, 1576, 1509, 1400, 1065 cmꢀ1. MS-EI m/z (%): 705
(5), 322 (18), 169 (7), 95 (100), 77 (10), 39 (15). Elemental analysis
Anal. Calc. for C36H26CuN4O4S2 (705.07): C, 61.22; H, 3.71; N, 7.93;
S, 9.08. Found: C, 61.10; H, 3.76; N, 7.98; S, 9.13%.
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4.3.6. Bis(N,N-diphenyl-N0-benzoylthioureato)copper(II) (2f)
Yield: 73%. Green solid; mp: 220–221 °C. IR (KBr):
m = 3061,
(b) F. Emen, U. Flörke, N. Külcü, H. Arslan, Acta Crystallogr., Sect. E59 (2003)
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3028, 1588, 1512, 1421, 1255 cmꢀ1. MS-EI m/z (%): 726 (100),
395 (23), 331 (42), 212 (30), 195 (3), 105 (34). Elemental analysis
calcd (%) for C40H30CuN4O2S2 (725.11) C, 66.14; H, 4.16; N, 7.71; S,
8.83. Found: C, 66.02; H, 4.11; N, 7.76; S, 8.88.
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(2002) 74;
4.3.7. Bis(N,N-dibenzyl-N0-benzoylthioureatocopper(II) (2g)
Yield: 83%. Lime green solid; mp: 160–162 °C. IR (KBr):
m
= 3061, 3028, 1588, 1512, 1421, 1255 cmꢀ1. MS-EI m/z (%): 781
(100), 448 (27), 359 (29), 196 (12), 105 (2). Elemental analysis Anal.
Calc. for C44H38CuN4O2S2 (781.17): C, 67.54; H, 4.89; N, 7.16; S,
8.20. Found: 67.42; H, 4.86; N, 7.22; S, 8.52%.
(b) T.J. Egan, K.R. Koch, P.L. Swan, C. Clarkson, D.A. Van Schalkwyk, P.J. Smith, J.
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(c) W. Zhou, Y. Wen, L. Xie, X. Cheng, J. Inorg. Biochem. 99 (2005) 1314;
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Soc., Dalton Trans. (2002) 3656;
4.3.8. Bis(N,N-diethyl-N0-benzoylthioureatocopper(II) (2h)
Yield: 82%. Lime green solid; mp: 110–115 °C. IR (KBr):
m
= 3059, 2979, 1585, 1493, 1413, 1168 cmꢀ1. MS-EI m/z (%): 534
(e) H. Arslan, N. Duran, G. Borekci, C.O. Koray, C. Akbay, Molecules 14 (2009)
519;
(100), 235 (25), 105 (3). Elemental analysis Anal. Calc. for
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C
24H30CuN4O2S2 (533.11): C, 53.96; H, 5.66; N, 10.49; S, 12.00.
Found: C, 53.84; H, 5.62; N, 10.60; S, 12.05%.
Acknowledgements
(c) H. Pérez, Y. Mascarenhas, O. Estévez-Hernández, S. Santos Jr., J. Duque, Acta
Crystallogr., Sect. E64 (2008) o695;
(d) O. Estévez-Hernández, J. Duque, H. Pérez, S. Santos Jr., Y. Mascarenhas,
Acta Crystallogr., Sect. E65 (2009) o929.
This work was supported by the MICINN of Spain (Project
CT2008-00795/BQU, Consolider-Ingenio 2010C-07-25200) and
CTQ2009-07758. M. Suárez is grateful to SAB2010-0132 from Min-
isterio de Educación de España. The authors thank the Instituto de
Química, UNAM, México, for allowing the X-ray data collection.
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Appendix A. Supplementary data
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CCDC 689278, 689308 and 755315 contains the supplementary
crystallographic data for complex 1a, 2a, and 2c, respectively.
m.ac.uk/conts/retrieving.html, or from the Cambridge Crystallo-
graphic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK;
fax: +44 1223 336 033; or e-mail: deposit@ccdc.cam.ac.uk. Supple-
mentary data associated with this article can be found, in the on-
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