Organometallics
Communication
Scheme 3. Proposed Catalytic Cycle
(8) Hreczycho, G.; Frackowiak, D.; Pawluc, P.; Marciniec, B.
Tetrahedron Lett. 2011, 52, 72.
(9) Hreczycho, G.; Pawluc, P.; Marciniec, B. New J. Chem. 2011, 35, 2743.
́
thoroughly explored and will have a strong impact on well-
investigated silicon chemistry.
(10) Catalytic Ge−O−Ge synthesis and stoichiometric E−O−E′
(E, E′ = Si, Ge, Sn) bond formation using a Mo complex was very
recently reported: Arias-Ugarte, R.; Sharma, H. K.; Morris, A. L. C.;
Pannel, K. H. J. Am. Chem. Soc. 2012, 134, 848.
(11) (a) Itazaki, M.; Ueda, K.; Nakazawa, H. Angew. Chem., Int. Ed.
2009, 48, 3313. (e) ibid, 48, 6938. (b) Sharma, H. K.; Pannell, K. H.
Angew. Chem., Int. Ed. 2009, 48, 7052. (c) Zhou, S.; Junge, K.; Addis,
D.; Das, S.; Beller, M. Angew. Chem., Int. Ed. 2009, 48, 9507.
(d) Sunada, Y.; Kawakami, H.; Motoyama, Y.; Nagashima, H. Angew.
Chem., Int. Ed. 2009, 48, 9511.
(12) (a) Kopylova, L. I.; Ivanova, N. D.; Voronkov, M. G. Zh. Obshch.
Khim. 1985, 55, 1649. (b) Matsubara, K.; Iura, T.; Maki, T.; Nagashima, H.
J. Org. Chem. 2002, 67, 4985. (c) Sasakuma, H.; Motoyama, Y.;
Nagashima, H. Chem. Commun. 2007, 4916. (d) Hanada, S.; Motoyama,
Y.; Nagashima, Y. Tetrahedron Lett. 2006, 47, 6137. (e) Igarashi, M.;
Fuchigami, T. Tetrahedron Lett. 2001, 42, 1945. (f) Ohta, T.; Kamiya,
M.; Nobutomo, M.; Kusui, K.; Furukawa, I. Bull. Chem. Soc. Jpn. 2005,
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39, 1017. (h) Motoyama, H.; Mitsui, K.; Ishida, T.; Nagashima, H. J. Am.
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Chem. 2001, 113, 2187; Angew. Chem., Int. Ed. 2001, 40, 2129. (j) Sakai,
N.; Fuhji, K.; Konakahara, T. Tetrahedron Lett. 2008, 49, 6873. (k) Hanada,
S.; Ishida, T.; Motoyama, Y.; Nagashima, H. J. Org. Chem. 2007, 72,
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(13) Reactions of hydrosilane with thioamide catalyzed by Fe and
Mo complexes to form disilathiane were recently reported:
(a) Fukumoto, K.; Sakai, A.; Oya, T.; Nakazawa, H. Chem. Commun.
2012, 48, 3809. (b) Arias-Ugarte, R.; Sharma, H. K.; Metta-Magana,
A. J.; Pannell, K. H. Organometallics 2011, 30, 6506.
ASSOCIATED CONTENT
* Supporting Information
Text giving detailed experimental procedures and the character-
ization data for the products and a CIF file giving crystallographic
data for 8. This material is available free of charge via the Internet
■
S
AUTHOR INFORMATION
Corresponding Author
Notes
■
The authors declare no competing financial interest.
ACKNOWLEDGMENTS
■
This work was supported by a Challenging Exploratory Research
grant (No. 23655056) from the Ministry of Education, Culture,
Sports, Science and Technology of Japan.
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