Tetrahedron p. 6999 - 7006 (1991)
Update date:2022-08-03
Topics: Purification Introduction of chirality Verification Chiral Starting Material or Chiral Catalyst Synthesis of Methyl Epijasmonate Open the epoxide ring Convert Diol to Ester Transform to Methyl Epijasmonate Purification and Verification
Kitahara, Takeshi
Nishi, Tsunehiro
Mori, Kenji
Both the pure enantiomers of methyl epijasmonate 1 with potato-tuber inducing activity were synthesized stereoselectively starting from 2-oxabicyclo[3.3.0]-oct-6-en-3-one 6 in 20% yield through 11 steps.
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