160
[9] Xiao HB, Li H, Chen MJ, Wang L. A water-soluble D-
B. Liu et al. / Dyes and Pigments 95 (2012) 149e160
-A chromophore based on [27] Tian YP, Li L, Zhang JZ, Yang JX, Zhou HP, Wu JY, et al. Investigations and facile
p
dipicolinic acid: synthesis, pH-dependent spectral properties and two-photon
fluorescence cell imaging. Dyes Pigm 2009;83:334e8.
synthesis of a series of novel multi-functional two-photon absorption mate-
rials. J Org Chem 2007;17:3646e54.
[10] (a) Dong XH, Yang YY, Sun J, Liu ZH, Liu BF. Two-photon excited fluorescent
probes for calcium based on internal charge transfer. Chem Commun;
2009:3883e5;
[28] Wang G, Pu KY, Zhang XH, Li K, Wang L, Cai LP, et al. Star-shaped glycosylated
conjugated oligomer for two-photon fluorescence imaging of live cells. Chem
Mater 2011;23:4428e34.
(b) Hai Y, Chen JJ, Zhao P, Lv HB, Yu Y, Xu PY, et al. Luminescent zinc salen
complexes as single and two-photon fluorescence subcellular imaging probes.
Chem Commun 2011;47:2435e7.
[29] (a) Hrobárik P, Hrobáriková V, Sigmundová I, Zahradník Pavol, Fakis M,
Polyzos I, et al. Benzothiazoles with tunable electron-withdrawing strength
and reverse polarity: a route to triphenylamine-based chromophores with
enhanced two-photon absorption. J Org Chem 2011;76:8726e36;
(b) Jiang YH, Wang YH, Hua JL, Tang J, Li B, Qian SX, et al. Multibranched tri-
arylamine end-capped triazines with aggregationinduced emission and large
two-photon absorption cross-sections. Chem Commun 2010;46:4689e91.
[30] Demas JN, Crosby GA. Measurement of photoluminescence quantum yields.
J Phys Chem 1971;75:991e1024.
[11] Zheng QD, He GS, Paras NP. A novel near IR two-photon absorbing chromo-
phore: optical limiting and stabilization performances at an optical commu-
nication wavelength. Chem Phys Lett 2009;475:250e5.
[12] Kazuya O, Yoshiaki K. Design of two-photon absorbing materials for molecular
optical memory and photodynamic therapy. Org Biomol Chem 2009;7:
2241e6.
[13] Belfield KD, Liu Y, Negres RA, Fan M, Pan G, Hagan DJ, et al. Two-photon
photochromism of an organic material for holographic recording. Chem Mater
2002;14:3663e7.
[31] Gray TG, Rudzinski CM, Meyer EE, Holm RH, Nocera DG. Spectroscopic and
photophysical properties of hexanuclear rhenium(III) chalcogenide clusters.
J Am Chem Soc 2003;125:4755e70.
[32] Xu C, Webb WW. Measurement of two-photon excitation cross sections of
molecular fluorophores with data from 690 to 1050 nm. J Opt Soc Am B 1997;
13:481e91.
ꢁ
[14] Michael S, Michael F, Zeng CY, Valerica R. Real-time monitoring of two-photon
photopolymerization for use in fabrication of microfluidic devices. Lab Chip
2009;9:819e27.
[15] Lee KS, Kim RH, Yang DY, Park SH. Advances in 3D nano/microfabrication
using two-photon initiated polymerization. Prog Polym Sci 2008;33:631e81.
[16] Zhou WH, Kuebler SM, Braun KL, Yu TY, Cammack JK, Ober CK, et al. An
efficient two-photon-generated photoacid applied to positive-tone 3D
microfabrication. Science 2002;296:1106e9.
[17] Park SH, Yang DY, Lee KS. Two-photon stereolithography for realizing
ultraprecise three-dimensional nano/microdevices. Laser Photon Rev 2009;3:
1e2.
[18] Jiang YH, Wang YC, Wang B, Yang JB, He NN, Qian SX, et al. Synthesis, two-
photon absorption and optical limiting properties of multibranched styryl
derivatives based on 1,3,5-triazine. Chem Eur J 2011;17:2479e91.
[19] Ji ZQ, Li YJ, Pritchett TM, Makarov NS, Haley JE, Li ZJ, et al. One-photon pho-
tophysics and two-photon absorption of 4-[9,9-di-(2-ethylhexyl)-7-
diphenylaminofluoren-2-yl]-2,20:60,200-terpyridine and their platinum chlo-
ride complexes. Chem Eur J 2011;17:279e2491.
[20] Wang Bing, Wang YC, Hua JL, Jiang YH, Huang JH, Qian SX, et al. Starburst
triarylamine donor-acceptor-donor quadrupolar derivatives base-on cyano-
substituted diphenylaminestyrylbenzene: tunable aggregation-induced
emission colors and large two-photon absorption cross sections. Chem Eur J
2011;17:2647e55.
[33] Varnavski O, Goodson T, Sukhomlinova L, Twieg R. Ultrafast exciton dynamics
in a branched molecule investigated by time-resolved fluorescence, transient
absorption, and three-pulse photon echo peak shift measurements. J Phys
Chem B 2004;108:10484e92.
[34] Qiu DF, Zhao Q, Bao XY, Liu KC, Wang HW, Guo YC, et al. Electro-
polymerization and characterization of an alternatively conjugated
donoreacceptor metallopolymer: poly-[Ru(40-(4-(diphenylamino) phenyl)-
2,20:60,200-terpyridine)2]2þ. Inorg Chem Commun 2011;14:296e9.
[35] Hu ZJ, Yang JX, Tian YP, Zhou HP, Tao XT, Bao G, et al. Synthesis and optical
properties of two 2,20: 60,200-terpyridyl-based two-photon initiators. J Mol
Struct 2007;839:50e7.
[36] Hu ZJ, Yang JX, Tian YP, Tao XT, Tian L, Zhou HP, et al. Synthesis, structures,
and optical properties of two novel two-photon initiators derived from
2,20:60,200-terpyridine. Bull Chem Soc Jpn 2007;80:86e993.
[37] (a) Grabowski ZR, Krystyna R. Structural changes accompanying intra-
molecular electron transfer: focus on twisted intramolecular charge-transfer
states and structures. Chem Rev 2007;103:3899e4032;
(b) Woo HY, Liu B, Kohler B, Korystov D, Mikhailovsky A, Bazan GC. Solvent
affects on the two-photon absorption of distyrylbenzene chromophores. J Am
Chen Soc 2005;127:14721e9.
[21] Wild A, Winter A, Schlütter F, Schubert US. Advances in the field of
p
-
[38] Zhou HP, Zhou FX, Wu P, Zheng Z, Yu ZP, Chen YX, et al. Three new five-
coordinated mercury (II) dyes: structure and enhanced two-photon absorp-
tion. Dyes Pigm 2011;91:237e47.
[39] Drobizhev M, Karotki A, Dzenis Y, Rebane A, Suo Z, Spangler CW. Strong
cooperative enhancement of two-photon absorption in dendrimers. J Phys
Chem B 2003;107:7540e3.
conjugated 2,20:60,200-terpyridines. Chem Soc Rev 2011;40:1459e511.
[22] Constable EC. 2,20:60,200-Terpyridines: from chemical obscurity to common
supramolecular motifs. Chem Soc Rev 2007;36:246e53.
[23] Cummings SD. Platinum complexes of terpyridine: interaction and reactivity
with biomolecules. Coord Chem Rev 2009;253:1495e516.
[24] Ghosh S, Chaitanya GK, Bhanuprakash K, Nazeeruddin MK, Grätzel M,
Reddy PY. Electronic structures and absorption spectra of linkage isomers of
trithiocyanato(4,40,400-tricarboxy-2,20:6,200-terpyridine)ruthenium(II)
complexes: a DFT study. Inorg Chem 2006;45:7600e11.
[25] Eryazici I, Moorefield CN, Newkome GR. Square-planar Pd(II), Pt(II), and
Au(III) terpyridine complexes: their syntheses, physical properties, supra-
molecular constructs, and biomedical activities. Chem Rev 2008;108:
1834e95.
[40] Strickler JH, Webb WW. Three-dimensional optical data storage in refractive
media by two-photon point excitation. Opt Lett 1991;16:1780e2.
[41] Cammi R, Cossi M, Tomasi J. Analytical derivatives for molecular solutes. III.
HartreeeFock static polarizability and hyperpolarizabilities in the polarizable
continuum model. J Chem Phys 1996;104:4611e20.
[42] Shen YR. The principles of nonlinear optics. New York: Wiley; 1984.
[44] Olsen J, Jorgensen P. Linear and nonlinear response functions for an exact
state and for an MCSCF state. J Chem Phys 1985;82:3235e64.
[45] DALTON, a molecular electronic structure program, Release Dalton. see, http://
[26] Hayami S, Komatsu Y, Shimizu T, Kamihata H, Lee YH. Spin-crossover in
cobalt(II) compounds containing terpyridine and its derivatives. Coord Chem
Rev 2011;255:1981e90.