Tetrahedron Letters p. 5899 - 5902 (1991)
Update date:2022-09-26
Topics:
Lee
Oya
Snyder
Asymmetric oxidation of β-ketoesters by the benzoyl peroxide quench of their lithioenamines formed with (S)-valine t-butyl esters has been accomplished with good enantioselectivity for the formation of tertiary benzoate esters. This procedure thus enables generation of tertiary alcohols in protected form.
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