Journal of Organic Chemistry p. 7693 - 7699 (2012)
Update date:2022-08-04
Topics:
Liu, Lu
Sarkisian, Ryan
Xu, Zhenghu
Wang, Hong
Novel enamine-metal Lewis acid bifunctional catalysts were successfully applied to the asymmetric Michael addition of ketones to alkylidene malonates, offering excellent stereoselectivity (up to >99% ee and >99:1 dr). The asymmetric Michael addition of ketones to allylidene malonates was also achieved.
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