Bulletin of the Chemical Society of Japan p. 75 - 96 (1992)
Update date:2022-07-29
Topics: Conversion Experimental terms Allylic sulfones (E)-Vinylic sulfones Syn-effect
Hirata, Takaki
Sasada, Yoshihiro
Ohtani, Takashi
Asada, Takahiro
Kinoshita, Hideki
et al.
It was found that (E)-vinylic sulfones preferentially afford (Z)-allylic sulfones as kinetically-controlled products by treatment with a base under mild conditions, while (Z)-vinylic sulfones give (E)-allylic sulfones.Such stereochemical relationship was
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