Tetrahedron Letters p. 607 - 608 (1992)
Update date:2022-08-03
Topics:
Martinez, A. Garcia
Vilar, E. Teso
Barcina, J. Osio
Alonso, J. Manrique
Rodriguez, E.
et al.
The solvolysis of (-)-(1R)-2,2-dimethyl-3-oxotrifluoromethylsulfonyloxynorbornane <(-)-8> in 60percent ethanol takes place with cleavage of C-2/C-3 bond to afford a mixture of (-)-(1R)-3-(1-methylethylidene)cyclopentane carboxylic acid (-)-(1c) (56percent) and its corresponding ethyl ester (-)-1d (21percent).
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