Chemical and Pharmaceutical Bulletin p. 1146 - 1151 (1996)
Update date:2022-09-26
Topics:
Maezaki, Naoyoshi
Murakami, Manabu
Soejima, Motohiro
Tanaka, Tetsuaki
Imanishi, Takeshi
Iwata, Chuzo
Asymmetric desymmetrization of a prochiral 1,3-diol was established by diastereoselective C-O bond fission of the chiral α-sulfinyl acetal 6. Treatment of 6 with titanium tetrachloride afforded mainly 7a via an oxonium intermediate, while with lithium diisopropylamide 7b was selectively obtained via diastereoselective β-elimination followed by an olefin isomerization.
View MoreJiangxi Global Natural Spice Co., Ltd.
Contact:+86-796-8106598
Address:No.89, Wenshan Road,South Industrial Park, Jishui County,Jiangxi Province
Contact:+86 021-51698675
Address:1701, Jielong Plaza, No.618 Pingliang Rd, ShangHai,China
website:http://www.eastarchem.com/
Contact:1-800-898-2436
Address:1215 K Street, STE 1700
NingBO Hong Xiang Biochem.Co.Ltd
website:http://www.hxbiochem.com
Contact:0574-66003444
Address:Ning Bo Bei Lun
Jiangxi Lixin Pharmaceutical Co.,Ltd.
Contact:0798-8337222; 18979813215
Address:Jiangxi City, Jindezheng Province
Doi:10.1016/j.jphotochem.2012.05.014
(2012)Doi:10.1016/j.ejmech.2013.01.014
(2013)Doi:10.1016/j.ejmech.2013.01.015
(2013)Doi:10.1021/ja3108966
(2013)Doi:10.1016/j.bmcl.2012.10.140
(2013)Doi:10.1016/S0040-4020(01)88536-7
(1992)