Organic Letters p. 6000 - 6003 (2012)
Update date:2022-08-15
Topics:
Lauer, Matthew G.
Henderson, William H.
Awad, Amneh
Stambuli, James P.
The palladium-catalyzed oxidation of alkyl enol ethers to enals, which employs low loadings of a palladium catalyst, is described. The mild oxidation conditions tolerate a diverse array of functional groups, while allowing the formation of di-, tri-, and tetrasubtituted olefins. The application of this methodology to intramolecular reactions of alkyl enol ethers containing pendant alcohols provides furan and 2,5-dihydrofuran products.
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