Journal of Fluorine Chemistry p. 179 - 188 (1991)
Update date:2022-07-30
Topics:
Fisher, Raymond
Tipping, Antony E.
Thermolysis of the azo compound (CF3)2NOC(CF3)2N=NC(CF3)2ON(CF3)2 (1) alone at 140 deg C gives nitrogen, hexafluoroacetone and the hydrazine (CF3)2NN(CF3)2 via (CF3)2N<*> radical coupling in quantitative yield, while from decomposition in the presence of the alkenes CF2=CF2, CF2=CFCl and CF2=CHF (ca. 1:1 molar ratio) the major products are the dimer <(CF3)2NCF2CCl2>2, trimer (CF3)2N(CF2CFCl)2CFClCF2N(CF3)2 and a mixture of tetramers (CF3)2N(C2HF3)4N(CF3)2, respectively.The (CF3)2N<*> radicals generated from 1 can also be trapped with bromine < -> (CF3)2NBr> and nitroso compounds < -> (CF3)2NNRO<*> (R=CF3 and Ph)>, but with ethyne or benzene near-quantitative yields of the amine (CF3)2NH are obtained.
View MoreWuhan Fortuna Chemical Co.,Ltd
website:http://www.fortunachem.com
Contact:86-27-59207850
Address:Add: Room 2015, No.2 Building, Kaixin Mansion No.107 Jinqiao Avenue, Wuhan, China
Shijiazhuang Haotian Chemical Co., Ltd.
Contact:86-311-85044374
Address:293 Donggang Road
website:http://www.sjzthld.com
Contact:86-311-66699812
Address:NO.600 ZHONGSHAN EAST ROAD SHIJIAZHUANG
Nantong Auxin Electronic Technology Co., LTD
Contact:86-513-88760026
Address:NO.5-1, Aoxin Road, Haian Hi-tech Development Zone, Jiangsu Province, China
Contact:+86-371-86058576
Address:NO.32, Jingsan Road, Zhengzhou, China
Doi:10.1016/j.tet.2012.06.009
(2012)Doi:10.1007/s11172-012-0048-z
()Doi:10.1007/s00044-017-2008-5
(2017)Doi:10.1007/s11426-012-4602-1
(2012)Doi:10.1007/s11164-012-0933-y
(2013)Doi:10.1055/S-0032-1317115
(2012)