Synthesis p. 387 - 390 (1992)
Update date:2022-07-29
Topics:
Frey
1,2,3-Tris(arylmethylene)cyclohexanes (eleven examples) are prepared by aldol condensation from aromatic aldehydes and cyclohexanones, followed by Wittig olefination. They are rearranged nearly quantitatively by gasous hydrogen bromide to 1,2,3-tris(arylmethyl)benzenes.
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Doi:10.1016/0040-4039(90)80138-C
(1990)Doi:10.1007/s00044-012-0366-6
(2013)Doi:10.1016/0022-328X(93)83013-L
(1993)Doi:10.1002/ejoc.201200518
(2012)Doi:10.3987/COM-12-12564
(2012)Doi:10.1246/bcsj.65.978
(1992)