Tetrahedron p. 4483 - 4494 (1995)
Update date:2022-08-04
Topics:
Suzuki, Keisuke
Hasegawa, Takayuki
Imai, Takahiro
Maeta, Hideki
Ohba, Shigeru
For generating cationic zirconocene species that are useful for organic synthesis, AgAsF6 proved to be an efficient catalyst that serves as a safe alternative to AgClO4. Scope and limitation is discussed on this new catalyst in the processes including (1) alkyl/alkenyl transfer reaction from organozirconocene chloride to aldehyde, (2) two- and four-carbon homologation of aldehyde, (3) dual synthetic methods of 1,3-dienes from aldehydes/ketones via 1,3-bimetallic species, and (4) three-component alkylative cycloaddition via o-quinodimethane species.
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Doi:10.1021/ja00881a015
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(2013)Doi:10.1007/s10593-015-1653-1
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(2013)Doi:10.1007/s11164-017-2870-2
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