Tetrahedron Letters p. 3261 - 3264 (1992)
Update date:2022-07-30
Topics: Synthesis alkenes Aziridines N-Methoxy N-H
Vedejs, Edwin
Sano, Hiroshi
Electron-rich alkenes are converted into N-methoxyaziridines by treatment with HN(OCH3)2 and trimethylsilyl triflate.Reduction with Li/ammonia affords the N-H aziridines. Key words: Aziridine; N-methoxyaziridine; N-methoxycaprolactam; dimethoxyamine; nitrenium ion
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(1987)