Journal of the American Chemical Society p. 6142 - 6148 (2013)
Update date:2022-08-04
Topics:
Grayson, Matthew N.
Goodman, Jonathan M.
1,1'-Bi-2-naphthol (BINOL)-derived phosphoric acids catalyze the asymmetric propargylation of aldehydes. Density functional theory (DFT) calculations showed that the reaction proceeds via a six-membered transition structure (TS) in which the catalyst Bron
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