Journal of Organometallic Chemistry p. 35 - 44 (1992)
Update date:2022-08-04
Topics:
Huppmann, Frank
Maringgele, Walter
Kottke, Thomas
Meller, Anton
Subvalent species of silicon have been generated by the dehalogenation of dichloro-bis(2,6-dimethyl-piperidino)silane (I), dichloro-bis(diethylamino)silane and dichloro(diisopropylamino))methylsilane (VI) with Na/K alloy in hexane containing benzene or biphenyl.From the reaction mixtures products formed by insertion into CH bonds of the aromatic compounds, have been isolated or detected as the aryl substituted aminosilanes (II, IV, VII and IX) and the bis(aminosilanyl)phenylenes (V and VIII).Futhermore benzo
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