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step means of synthesizing chelating bisphosphine ligands. The
reaction is actually highly selective for alkyl halides, and aryl
halides are inert. The X-ray crystal analysis of the reaction
products indicated a SN2 reaction mechanism with congura-
tion inversion. In this way, the reaction provides a generic
method for using chiral secondary alcohols to produce C–P
bond with stereocontrol. Further investigation will be carried
out on using tertiary alkyl electrophiles as the reaction
substrates with more P–H compounds.
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Acknowledgements
Our study was supported by the National Natural Science
Foundation of China (21402179, 91426302), and the Science
Challenge Project (JCKY2016212A504). We also thank Prof.
Shuao Wang and Prof. Juan Diwu for the X-ray crystal analysis
and helpful discussions.
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