Beilstein Journal of Organic Chemistry p. 1217 - 1225 (2013)
Update date:2022-08-02
Topics:
Too, Pei Chui
Tnay, Ya Lin
Chiba, Shunsuke
We report herein Cu-catalyzed aerobic oxygenation of aliphatic C-H bonds with hydroperoxides, which proceeds by 1,5-H radical shift of putative oxygen-centered radicals (O-radicals) derived from hydroperoxides followed by trapping of the resulting carboncentered radicals with molecular oxygen.
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Doi:10.1039/c3ra42296h
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