Journal of Organometallic Chemistry p. 183 - 194 (1993)
Update date:2022-07-30
Topics:
Imada, Yasushi
Shibata, Ou
Murahashi, Shun-Ichi
Rhodium-catalyzed carbonylation of allyl phosphates under CO (20 atm) at 50 deg C proceeds very efficiently in the presence of amines, alcohols, and water to give the corresponding β,γ-unsaturated amides, esters, and acids, respectively.These carbonylations occur with high regioselectivity at the less substituted carbon of allyl unit to give linear β,υ-unsaturated acid derivatives.
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