Bulletin of the Chemical Society of Japan p. 2297 - 2300 (1997)
Update date:2022-08-02
Topics:
Yorimitsu, Hideki
Hayashi, Yasuhiro
Tang, Jun
Shinokubo, Hiroshi
Oshima, Koichiro
The unsymmetrical diorganomanganeses(II) (R1R2Mn) and magnesium triorganomanganates(II) (R21R2MnMgX) reacted with 2-cyclohexen-1-one to produce the 1,4-addition products in moderate to good yields. The approximate reactivity order obtained from the product distribution was CH2=CHCH2 > PhS > n-Bu > Ph > Me, Me3SiCH2, n-C6H13-CΞC. In contrast, the reactivity order for the addition of these reagents to cyclohexanecarbaldehyde was CH2=CHCH2 > Ph > Me > n-Bu > n-C6H13CΞC > Me3SiCH2.
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