Tetrahedron p. 1045 - 1062 (1994)
Update date:2022-09-26
Topics:
Kusuda, Shinya
Ueno, Yoshio
Toru, Takeshi
Both enantiomers of optically pure secondary allylic alcohols can be conveniently prepared by the diastereoselective reaction of the α-sulfinyl carbanion of p-tolyl 2-(trialkylsilyl)ethyl sulfoxides or tert-butyl 2-(trimethylsilyl)ethyl sulfoxide with aldehydes followed by either fluoride-induced desilylsulfinylation or thermal elimination of the sulfinyl group.
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Doi:10.1016/S0040-4039(00)60747-5
(1994)Doi:10.1021/ja413194z
(2014)Doi:10.1021/jm401552y
(2014)Doi:10.1021/jo00094a048
(1994)Doi:10.1002/adsc.201300493
(2013)Doi:10.1016/0022-328X(93)83409-O
(1993)