EFFICIENT RACEMIZATION OF 1-PHENYLETHYLAMINE
2405
9. Geukens, I., Plessers, E., Seo, J.W., and De Vos, D.E.,
1-(4-Methoxyphenyl)ethylamine (VIII). White
powder. Yield 93%. ESI-MS: m/z 151.85 ([M + H]+,
C9H14NO is 152.11). H NMR spectrum (400 MHz,
Eur. J. Inorg. Chem., 2013, pp. 2623–2628.
1
10. Parvulescu, A., Vros, D.De, and Jacobs, P., Chem.
Commun., 2005, pp. 5307–5309.
CDCl3, TMS), δ, ppm: 6.86–7.28 m (4H), 4.09 m (1H),
3.77 s (3H), 1.37 d (3H).
11. Ebbers, E.J., Ariaans, G.J.A., Houbiers, J.P.M.,
Bruggink, A., and Zwanenburg, B., Tetrahedron, 1997,
vol. 53, pp. 9417–9476.
1-(4-Fluorophenyl)ethylamine
(IX).
White
powder. Yield 90%. ESI-MS: m/z 139.91 ([M + H]+,
1
12. Gastaldi, S., Escoubet, S., Vanthuyne, N., Gil, G., and
C8H11FN is 140.09). H NMR spectrum (400 MHz,
Bertrand, M.P., Org. Lett, 2007, no. 9, pp. 837–839.
CDCl3, TMS), δ, ppm: 7.00–7.27 m (4H),4.25 m
13. Poulhes, F., Vanthuyne, N., Bertrand, M.P., Gastaldi, S.,
and Gil, G., J. Org. Chem., 2011, vool. 76, pp. 7281–
7286.
(1H),1.37 d (3H).
1,2,3,4-Tetrahydronaphthyl-l-amine (X). Pink
powder. Yield 90%. ESI-MS: m/z 147.98 ([M + H]+,
C10H14N is 148.11). H NMR spectrum (400 MHz,
CDCl3, TMS), δ, ppm: 7.22–8.10 m (4H), 1.50 m (2H),
4.36 m (1H), 2.77 t (2H), 1.90 m (2H).
14. Ahn, Y., Kо, S.В., Kim, M.J., and Park, J., Coord.
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1
15. Jansen, M.L.J.R., Bayer Aktiengesellschaft (Lever-
kusen, DE) 1993, US 5183939.
ACKNOWLEDGMENTS
16. Bison, K.B.G., Heinzelmann, W., and Wolfes, W.,
Dynamit Nobel Aktiengesellschaft (Troisdorf, DE),
1981, US 4252744.
This work was financially supported by the the
Projects of Science Technology Department of Zhejiang
Province (instead of the Science and Technology Plan
of Zhejiang Province) (no. 2013C31119) and by
Zhejiang Apeloa Medical Technology Co. Ltd.
17. Kim, M.J., Kim, W.H., Han, K., Choi, Y.K., and Park, J.,
Org. Lett, 2007, no. 9, pp. 1157–1159.
18. Reetz, М.Т. and Schimossek, K., Chimia, 1996, vol. 50,
pp. 668–669.
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RUSSIAN JOURNAL OF GENERAL CHEMISTRY Vol. 83 No. 12 2013