Tetrahedron Letters p. 4015 - 4018 (1996)
Update date:2022-08-03
Topics:
Konda, Yaeko
Toida, Tsuneyuki
Kaji, Eisuke
Takeda, Kazuyoshi
Harigaya, Yoshihiro
First total synthesis of monoterpene diglycosides, neohancosides A (1) and B (2) from Cynanchum hancockianum were achieved stereoselectively using fluoride as a glycosyl donor. The absolute configurations of 1 and 2 were determined by enzymatic degradation of synthetic intermediates.
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