ACS Catalysis
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chemoselectivity towards aryl ethers over aliphatic ones.
These features render the new deprotection methodology
potentially useful in the protection of ‐OH and COOH in
organic synthesis. Furthermore, the key component of the
process is the uncovering of Pd(OAc)2 as a promoter, ca‐
pable of switching the reactivity of NaH from base to a
nucleophile. Further studies along this direction are cur‐
rently underway in our laboratories and will be reported
in due course.
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Experiment details and spectroscopic data. This material is
available free of charge via the Internet at
AUTHOR INFORMATION
Corresponding Author
zhangshilei@suda.edu.cn;
Author Contributions
‡These authors contribute equally to this work.
Funding Sources
The authors declare no competing financial interests.
ber, D. J.; Rincón, J. A.; Brown, R. C. D. Electrochemical Deprotec‐
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ACKNOWLEDGMENT
This work was supported by the National Natural Science
Foundation of China (21202112, 21738002, and ), Suzhou Sci‐
ence and Technology Project (Grant No. ZXY201435), PAPD
(A Project Funded by the Priority Academic Program Devel‐
opment of Jiangsu Higher Education Institutions), the Natu‐
ral Science Foundation of Shandong Province (ZR2016BM07)
and the Qingdao Special Research Foundation of Science and
Technology (16‐1‐2‐29‐nsh).
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