Journal of the American Chemical Society p. 9927 - 9934 (1994)
Update date:2022-08-04
Topics: Synthesis Optically active Aldol Reaction Photocyclization 4-substituted 2-aminobutyrolactones Homoserines Chromium aminocarbene complexes
Schmeck, Carsten
Hegedus, Louis S.
Aldol reactions of optically active chromium aminocarbene complexes proceeded with moderate to high diasteroselectivity. Photolysis of the aldol product gave optically active 4-substituted 2-aminobutyrolactones which could be hydrolyzed to γ-hydroxy-α-ami
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