Tetrahedron Letters p. 6047 - 6050 (1994)
Update date:2022-07-30
Topics: PPL-Catalyzed Enzymatic Asymmetrization 2-Substituted Prochiral 1,3-Diol Remote Chiral Functionality Eutomers of SCH 45012
Lovey, Raymond G.
Saksena, Anil K.
Girijavallabhan, Viyyoor M.
Porcine pancreatic lipase (PPL) catalysis has been used to establish both stereocenters of the cis-(tetrahydrofuranylmethyl) tosylate 4. In addition to the enzymatic differentiation of the hydroxyl groups of the pro-chiral 1,3-diol segment of 2, successful enzymatic resolution of the racemic diol 10 provided an alternate route to the important precursor 1.
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(1995)Doi:10.1016/0957-4166(95)00194-T
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(1995)Doi:10.1080/00397919508011814
(1995)