Journal of the American Chemical Society p. 6296 - 6299 (1986)
Update date:2022-08-03
Topics:
Rahman, M.
McKee, Michael L.
Shevlin, Philip B.
The reaction of arc generated carbon atoms with CF4 at 77 K in the presence of alkene trapping agents results in the formation of fluorocyclopropanes and 1,1-difluoroalkanes.The fluorocyclopropanes are postulated to arise by addition of CF to the double bond generating a cyclopropyl radical which abstracts H.CF adds stereospecifically to olefins and gives both cis and trans fluorocyclopropanes with the trans generally predominating.The 1,1-difluoroalkanes are postulated to be the result of a 3CF2 reaction.In the presence of oxygen, the CF is oxidized to CO2, and the 3CF2 gives carbonyl fluoride.
View MoreHangzhou Ocean Chemical Co., Ltd.
website:http://www.hzoceanchem.com
Contact:+86-571-88025872, 28272092, 28272096
Address:Room 623 ,Building No 1 , COFCO Radius Commercial Center Xiwen Road, Xiacheng District, Hangzhou, Zhejiang Province, China
Jiande City Silibase Silicone New Material Manufacture Co., Ltd.
Contact:15967177856
Address:Genglou Industrial Development Area
Henan Tianfu Chemical Co., Ltd.
website:http://www.tianfuchem.com
Contact:86-371-55170693/55170694
Address:Zhengzhou International Trade New Territory,Jinshui District,Zhengzhou ,China
Contact:0086-29-89196322
Address:North of the Fifth Keji Road, Hi-Tech Industrial Zone, Xi'an City, Shaanxi Province, China
Tianjin Realet Chemical Technology Co.,Ltd.
website:http://www.realetchem.com
Contact:+86-022-58788819
Address:shuanggang industrial park
Doi:10.1021/jm00308a068
(1968)Doi:10.1021/jm00014a005
(1995)Doi:10.1021/om00110a044
(1989)Doi:10.1016/0040-4039(94)85300-2
(1994)Doi:10.1016/0040-4039(94)88435-8
(1994)Doi:10.1016/S0040-4039(01)84121-6
(1966)