Journal of the American Chemical Society p. 10525 - 10532 (1994)
Update date:2022-08-02
Topics: Synthetic studies Derivatives Substituted Route 1,6-methano[10]annulene
Barrett, David G.
Liang, Gui-Bai
McQuade, D. Tyler
Desper, John M.
Schladetzky, Kurt D.
Gellman, Samuel H.
A new synthetic route to the 1,6-methano[10]annulene skeleton has been developed. The key step in this route is the semi-benzylic Favorskii rearrangement of a [4.4.2]propellane to a [4.4.1]propellane. The methodology discussed here provides access to 1,6-
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