Journal of Fluorine Chemistry p. 83 - 86 (1995)
Update date:2022-08-05
Topics:
Laduron, Frederic
Janousek, Zdenek
Viehe, Heinz, G.
The syntheses of α- and β-trifluoromethyl epoxysulfones 1 and 2 are described.Compound 1 reacts with nucleophiles and bis-nucleophiles to furnish trifluoromethyl ketones and trifluoromethyl heterocycles in good yield, while its isomer 2 leads to the opposite thiazole regioisomers with thioamides. - Keywords: Trifluoromethyl epoxysulfones; Heterocyclisation; Regioisomers; NMR spectroscopy; IR spectroscopy
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Doi:10.1021/jo952093m
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(1994)