Tetrahedron Letters p. 4059 - 4062 (1995)
Update date:2022-08-04
Topics:
Compain, Philippe
Enantioenriched 2-allyl- and 2-(3-trimethylsilylpropargyl)-2-hydroxycyclohexanone were respectively obtained by resolution from the corresponding diastereomeric acetal derived from C2-symmetrical diol or from the camphanate ester. Study of the rearrangement of their corresponding imine derivatives has shown that it occurred with complete retention of the stereogenicity.
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