Tetrahedron p. 11011 - 11026 (1998)
Update date:2022-07-30
Topics:
Akita, Hiroyuki
Chen, Cheng Yu
Kato, Keisuke
A stereoselective synthesis of the versatile chiral synthon possessing two stereogenic centers, (2S,3S)-11 (>99% ee) was achieved by using chemo- enzymatic method. The conversion of (2S,3s)-11 into the homochiral intermediates (2S,3S,4S)-25 and (2S,3S,4S)-27 corresponding to the N-terminal amino acid moiety of nikkomycin B(1) and their application to the formal total synthesis of nikkomycin B(1) are described.
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