A convenient preparation of pentafluorophenyl( fluoro) silanes: Reactivity of pentafluorophenyltrifluorosilane

DOI: 10.1016/0022-328X(95)05676-G

Source and publish data:

Journal of Organometallic Chemistry p. 155 - 164 (1996)

Update date:2022-08-04

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Authors:

Frohn Frohn

Giesen Giesen

Klose Klose

Lewin Lewin

Bardin Bardin

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Article abstract of DOI:10.1016/0022-328X(95)05676-G

Pentafluorophenyl(fluoro)silanes (C₆F₅)_nSiF_4-n (n = 1, 2) were prepared from the corresponding ethoxysilanes by sequential chlorodeethoxylation with SOCl₂ and fluoridation of chlorosilanes with SbF₃. The conversion of C₆F₅Si(OEt)₃ and C₆F₅SiCl₃ into C₆F₅SiF₃ with anhydrous HF was described. Some reactions of C₆F₅SiF₃ with electrophiles and nucleophiles were studied.

Full text of DOI:10.1016/0022-328X(95)05676-G

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Article Doi

A convenient preparation of pentafluorophenyl( fluoro) silanes: Reactivity of pentafluorophenyltrifluorosilane

DOI: 10.1016/0022-328X(95)05676-G

Source and publish data:

Authors:

Article abstract of DOI:10.1016/0022-328X(95)05676-G

Full text of DOI:10.1016/0022-328X(95)05676-G

Products guided by the article

R&D Labs maybe for 174743-11-4

Relevant to this article

Syntheses and Reactions of the Diethyl α-Alkynylmalonates Involving the Generation of Conjugated Allenyl Esters as the Latent Active Species: A New Approach to the Development of Cysteine Proteinase Inhibitors

Bis-phosphites and bis-phosphinites based on distally-functionalised calix[4]arenes: Coordination chemistry and use in rhodium-catalysed, low-pressure olefin hydroformylation

5-Exo-dig radical cyclization of enediynes: The first synthesis of tin-substituted benzofulvenes

Practical, stereoselective synthesis of palinavir, a potent HIV protease inhibitor

β-lactams from D-erythrose-derived imines: A convenient synthesis of 2,3-diamino-2,3-dideoxy-d-mannonic-acid derivatives

Development of the 1,2,4-triazole-based anticonvulsant drug candidates acting on the voltage-gated sodium channels. Insights from in-vivo, in-vitro, and in-silico studies