Tetrahedron p. 1059 - 1068 (1982)
Update date:2022-09-26
Topics:
Russell, Glen A.
Mudryk, Boguslaw
Ros, Francisco
Jawdosiuk, Mikolaj
The reaction of mono-enolate anions with O2NCMe2X where X=Cl, NO2, p-MePhSO2 yield coupling (RCOCH(R')(CMe2NO2) and enolate dimerization products (RCOCH(R')CH(R')COR) by free radical chain mechanisms involving bimolecular substitution or electron transfer reactions between the enolate anion and the intermediate nitro alkane radical anion (XCMe2NO2<*>(1-)).
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Doi:10.1016/0040-4020(68)88069-X
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