Journal of Organometallic Chemistry p. 219 - 227 (1997)
Update date:2022-07-29
Topics:
Harrity, Joseph P. A.
Kerr, William J.
Middlemiss, David
Scott, James S.
During attempts to synthesise the 2-hydroxy-1,4-naphthoquinone, parvaquone, 1, a novel chromium-mediated method for the synthesis of functionalised β-lactones from propargyl alcohols has been discovered. Additionally, using both dry state and ultrasound conditions, the total synthesis of parvaquone (1) has been achieved; the most efficient techniques deliver this target compound in up to 46% overall yield over, as low as, two synthetic processes.
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