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Graphical Abstract
Chin. J. Catal., 2021, 42: 2059–2067 doi: 10.1016/S1872‐2067(21)63853‐6
Zirconium‐hydride‐catalyzed site‐selective hydroboration of amides for the synthesis of amines: Mechanism, scope, and
application
Bo Han, Jiong Zhang, Haijun Jiao *, Lipeng Wu *
Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, China; Leibniz‐Institut für Katalyse, Germany;
University of Chinese Academy of Sciences, China
operando IR, NMR spectroscopy studies, DFT calculations
Zr-H mediated C–N bond cleavage-reforming and then C-O cleavage
Selective hydroboration of amides with tolerance of other more active functional groups
Amine synthesis via amide hydroboration at room temperature catalyzed by earth‐abundant‐metal catalyst Zr‐H is achieved. Readily
reducible functional groups, such as esters, alkynes, and alkenes are well‐tolerated.