H. Werner et al. / Journal of Organometallic Chemistry 565 (1998) 231–241
241
e A−3. Detailed crystallographic data (excluding struc-
˚
[8] M.I. Bruce, in: G. Wilkinson, F.G.A. Stone, E.W. Abel (Eds.),
Comprehensive Organometallic Chemistry, vol. 2, Pergamon,
Oxford, 1982, p. 693.
[9] N.R. Champness, W. Levason, M. Webster, Inorg. Chim. Acta
208 (1993) 189.
ture factors) for the structure of 4 and 17 have been
deposited with the Cambridge Crystallographic Data
Centre as supplementary publication no. 101236.
Copies of the data can be obtained free of charge on
application to the Director, CCDC, 12 Union Road,
Cambridge CB2 1EZ, UK (email: deposit@
chemcrys.cam.ac.uk).
[10] C. Gru¨nwald, M. Laubender, J. Wolf, H. Werner, J. Chem. Soc.
Dalton Trans. (1998) 833.
[11] A.D. Harris, S.D. Robinson, Inorg. Chim. Acta. 42 (1980) 25.
[12] (a) P.G. Douglas, B.L. Shaw, J. Chem. Soc. A (1970) 1556. (b)
E.W. Ainscough, T.A. James, S.D. Robinson, J.N. Wingfield, J.
Organomet. Chem. 60 (1973) C63. (c) M. Preece, S.D. Robinson,
J.N. Wingfield, J. Chem. Soc. Dalton Trans. (1976) 613. (d) D.S.
Bohle, W.R. Roper, Organometallics 5 (1986) 1607. (e) S. Huh,
Y. Cho, M.-J. Jun, Polyhedron 13 (1994) 1887.
Acknowledgements
[13] W.P. Griffith, in: G. Wilkinson, R.D. Gillard, J.A. McCleverty
(Eds.), Comprehensive Coordination Chemistry, vol. 4, Perga-
mon, Oxford, 1987, p. 573.
[14] R.A. Cipriano, W. Levason, R.A.S. Mould, D. Pletcher, M.
Webster, J. Chem. Soc. Dalton Trans. (1990) 2609.
[15] H. Werner, M.A. Esteruelas, U. Meyer, B. Wrackmeyer, Chem.
Ber. 120 (1987) 11.
We thank the Deutsche Forschungsgemeinschaft
(SFB 347) and the Fonds der Chemischen Industrie for
financial support. We also gratefully acknowledge sup-
port by B. Weberndo¨rfer for valuable assistance during
the crystallographic work, by R. Schedl and C.P. Kneis
(DTA and elemental analyses) and by Degussa AG
(gifts of chemicals).
[16] A. Santos, J. Lopez, L. Matas, J. Ros, A. Galan, A.M. Echavar-
ren, Organometallics 12 (1993) 4215.
[17] J.P. Selegue, Organometallics 1 (1982) 217.
[18] (a) H. Werner, T. Rappert, Chem. Ber. 126 (1993) 669. (b) H.
Werner, T. Rappert, R. Wiedemann, J. Wolf, N. Mahr,
Organometallics 13 (1994) 2721. (c) H. Werner, A. Stark, P.
Steinert, C. Gru¨nwald, J. Wolf, Chem. Ber. 128 (1995) 49.
[19] (a) E.O. Fischer, H.J. Kalder, A. Frank, F.H. Ko¨hler, G.
Huttner, Angew. Chem. 88 (1976) 683; Angew. Chem. Int. Ed.
Engl. 15 (1976) 623. (b) H. Berke, G. Huttner, J. von Seyerl, Z.
Naturforsch. 36b (1981) 1277. (c) H. Berke, P. Ha¨rter, G.
Huttner, J. von Seyerl, J. Organomet. Chem. 219 (1981) 317. (d)
H. Berke, U. Gro¨ssmann, G. Huttner, L. Zsolnai, Chem. Ber.
117 (1984) 3432. (e) N. Pirio, D. Touchard, L. Toupet, P.H.
Dixneuf, J. Chem. Soc. Chem. Commun. (1991) 980. (f) A.
Wolinska, D. Touchard, P.H. Dixneuf, A. Romero, J.
Organomet. Chem. 420 (1991) 217. (g) H. Fischer, D. Reindl, J.
Roth, Z. Naturforsch. 49b (1994) 1207. (i) R. Aumann, B.
Jasper, R. Fro¨hlich, Organometallics 14 (1995) 3173. (j) V.
Cadierno, M.P. Gamasa, J. Gimeno, M. Gonza´lez-Cueva, E.
Lastra, J. Borge, S. Garcia-Granda, E. Pe´rez-Carreno,
Organometallics 15 (1996) 2137.
References
[1] (a) P. Schwab, N. Mahr, J. Wolf, H. Werner, Angew. Chem. 105
(1993) 1498; Angew. Chem. Int. Ed. Engl. 32 (1993) 1480. (b) P.
Schwab, N. Mahr, J. Wolf, H. Werner, Angew. Chem. 106
(1994) 82; Angew. Chem. Int. Ed. Engl. 33 (1994) 97. (c) H.
Werner, P. Schwab, E. Bleuel, N. Mahr, P. Steinert, J. Wolf,
Chem. Eur. J. 3 (1997) 1375. (d) P. Schwab, Dissertation,
Universita¨t Wu¨rzburg, 1994.
[2] (a) H. Werner, D.A. Ortmann, O. Gevert, Chem. Ber. 129 (1996)
411. (b) D.A. Ortmann, Dissertation, Universita¨t Wu¨rzburg, to
be submitted.
[3] (a) A. Araneo, S. Martinengo, Rend. 1st. Lomb. Sci. Lett. A99
(1965) 829. (b) N.J. Holmes, W. Levason, M. Webster, J. Chem.
Soc. Dalton Trans. (1997) 4223.
[4] N.R. Champness, W. Levason, Coord. Chem. Rev. 133 (1994)
115.
[5] H. Werner, C. Gru¨nwald, M. Laubender, O. Gevert, Chem. Ber.
129 (1996) 1191.
[20] B.E.R. Schilling, R. Hoffmann, D.L. Lichtenberger, J. Am.
Chem. Soc. 101 (1979) 588.
[21] M.A. Bennett, A.K. Smith, J. Chem. Soc. Dalton Trans. (1974)
233.
[22] H. Werner, P. Schwab, N. Mahr, J. Wolf, Chem. Ber. 125 (1992)
2641.
[6] (a) F. Faraone, V. Marsala, Inorg. Chim. Acta 27 (1978) L109.
(b) B. Demerseman, R. Le Lagadec, B. Guilbert, C. Renouard,
P. Crochet, P.H. Dixneuf, Organometallics 13 (1994) 2269.
[7] T.A. Stephenson, G. Wilkinson, J. Inorg. Nucl. Chem. 28 (1966)
945.
.
.