Molecules p. 13603 - 13613 (2014)
Update date:2022-07-31
Topics:
Yu, Siqi
Wang, Huan
Sledziewski, Jill E.
Madhira, Venkata N.
Takahashi, Cyrus G.
Leon, Michelle K.
Dudkina, Yulia B.
Budnikova, Yulia H.
Vicic, David A.
New well-defined, paramagnetic nickel complexes have been prepared and characterized by X-ray crystallography. The complexes were found to be active for the cross-coupling of alkyl electrophiles (especially ethyl 2-bromobutyrate) with alkyl Grignard reagents. The ligand architecture in these new complexes could potentially be rendered chiral, opening up future possibilities for performing asymmetric cross-coupling reactions.
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