Tetrahedron Letters p. 6911 - 6914 (1998)
Update date:2022-08-03
Topics:
Mochizuki, Takashi
Itoh, Etsuko
Shibata, Norio
Nakatani, Shogo
Katoh, Tadashi
Terashima, Shiro
The macrotricyclic part of roseophilin, a novel cytotoxic antibiotic, was efficiently synthesized starting with the known 3-formylpyrrole; the method features intramolecular alkylation to form the desired thirteen- membered carbocycle and base-induced int
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