3938
C. Luján, S.P. Nolan / Journal of Organometallic Chemistry 696 (2011) 3935e3938
c) T. Ritter, A. Hejl, A.G. Wenzel, T.W. Funk, R.H. Grubbs, Organometallics 25
Acknowledgements
(2006) 5740.
[8] For impressive E/Z selectivity using molybdenum systems, see: a) I. Ibrahem,
M. Yu, R.R. Schrock, A.H. Hoveyda, J. Am. Chem. Soc. 131 (2009) 3844;
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3844;
The EC is gratefully acknowledged for funding through the
seventh framework program (CP-FP 211468-2-EUMET). SPN is
a Royal Society Wolfson Research Merit Award holder.
d) S.J. Meek, R.V. O/’Brien, J. Llaveria, R.R. Schrock, A.H. Hoveyda, Nature 471
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Appendix. Supplementary material
[9] Primary metathesis involves the reaction of Ru catalyst with a terminal
olefin forming a Ru alkylidene species that will react with another olefin to
afford E- or Z-product. Secondary metathesis, on the other hand, involves
the reaction of the E-/Z-product with Ru catalysts resulting in the inter-
conversion of the product isomers towards the most thermodynamically
stable.
Supplementary data associated with this article can be found, in
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