Tetrahedron Letters p. 621 - 624 (2000)
Update date:2022-08-04
Topics:
Schuppan, Julia
Ziemer, Burkhard
Koert, Ulrich
An efficient, stereocontrolled synthesis of the C 18-C28 segment of apoptolidin has been achieved. Key steps are a stannous triflate-mediated aldol reaction, the acylation of a Weinreb amide with an E-alkenyl lithium reagent and the dihydroxylation of a C19-C20 double bond. (C) 2000 Elsevier Science Ltd.
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