Organometallics
Communication
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(7) For heterogeneous Pd-catalyzed cotrimerization of ethylene and
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(9) For Ni-catalyzed cotrimerization of ethylene and isocyanate, see:
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(10) (a) Park, J. D.; Benning, A. F.; Downing, F. B.; Laucius, J. F.;
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(16) (a) Baker, R. T.; Beatty, R. P.; Sievert, A. C.; Wallace, R. L., Jr.
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(17) The NMR yields of 6 and 7 were 69 and 64%, respectively. See
also the Supporting Information for details.
(18) See the Supporting Information for experimental details, an
ORTEP drawing of 10, and optimization of the catalytic reaction
conditions.
(19) No formation of 3 was observed in the catalytic reaction in
which the two kinds of gases were pressurized in the reverse order.
(11) (a) Ohashi, M.; Kambara, T.; Hatanaka, T.; Saijo, H.; Doi, R.;
Ogoshi, S. J. Am. Chem. Soc. 2011, 133, 3256−3259. (b) Ohashi, M.;
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(c) Ohashi, M.; Shibata, M.; Saijo, H.; Kambara, T.; Ogoshi, S.
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(12) Related C−F bond activation of fluorinated compounds. See
also: (a) Ohashi, M.; Doi, R.; Ogoshi, S. Chem. - Eur. J. 2014, 20,
2040−2048. (b) Ohashi, M.; Shibata, M.; Ogoshi, S. Angew. Chem., Int.
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(13) Related formation of pentafluoronickelacyclopentanes. See also:
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D
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