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New Journal of Chemistry
Page 7 of 10
DOI: 10.1039/C7NJ04836J
Journal Name
ARTICLE
9
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A 20-mL flask was charged with a mixture of aryl halide (1.0 or
0.3 mmol), phenylboronic acid (1.5 or 3.0 mmol), base (2.0 or
1.5 mmol), and 0.1-0.01 mol% palladium-NHC nanoparticles in
5 mL of water. After stirring at 60 °C for the required time, the
reaction mixture was cooled to room temperature and
centrifuged at 3000 rpm for 10 min. The supernatant was
removed, and the residue was dissolved in dichloromethane
(20 mL) and dried over Na2SO4. The resulting mixture was
analyzed by gas chromatography using anisole as an internal
standard or purified by flash chromatography to give the
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desired product.Complexes 4a
1H and 13C NMR, the NMR data and spectrums are listed in the
Electronic Supplementary Information (ESI). Among 4a 4r, 4c
4d 4e 4f 4j 4k 4o 4p and 4q are new compounds, other
-4r have been characterized by
11 (a) L. A. Schaper, S. J. Hock, W. A. Herrmann, F. E. Kühn,
Angew. Chem., Int. Ed., 2013, 52, 270; (b) J. M. Asensio, P.
-
,
,
,
,
,
,
,
Gómez-Sal, R. Andrés, E. de Jesús, Dalton Trans., 2017, 46
,
complexes have been reported by other literature (see ESI).
6785; N. Sun, M. Chen, L. Jin, W. Zhao, B. Hu, Z. Shen, X. Hu,
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Conflicts of interest
The authors declare no competing financial interest.
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,
,
7
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Acknowledgements
We gratefully acknowledge the support from the Natural
Science Foundation of Zhejiang Province (LQ14B020003) and
the National Natural Science Foundation of China (81571799
and 81773193).
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