Journal of Organometallic Chemistry p. 133 - 138 (1996)
Update date:2022-08-05
Topics:
Tuulmets, Ants
Mikk, Marvi
Panov, Dmitri
Toluene solutions of alkylmagnesium chlorides partially solvated by diethyl ether were investigated. Primary and secondary alkyl chlorides can be converted into Grignard reagents in good yields in the presence of small amounts of ether (less than one mole per mole of halide). Tertiary chlorides form only monosolvated organomagnesium compounds. Ultrasound accelerates the process. The reagents obtained are heterogeneous, but the solubilities of the partially solvated complexes in toluene are fairly high. Some of the reagents disproportionate to magnesium chloride and the dialkylmagnesium. The extent of disproportionation decreases with an increase in the concentration of the reagent or in the steric requirements of the alkyl moiety.
View MoreJunkai (Tianjin) Chemical Co., Ltd.
website:http://www.junkaichem.com
Contact:86-22-85689515
Address:Room 8-501, Building K2, The Hi-Tech Green Industrial Base, No.6, 6th Road, Hi-Tech Development Road, Tianjin Hi-Tech IndustrialPark, Tianjin, China.
QINGDAO DEVELOP chemistry Co.,Limited
Contact:+86-532-85807910
Address:98#Nanjing Road, Qingdao, China 266071
Chengda Pharmaceuticals Co., Ltd.
Contact:+86-573-84601188
Address:hengshan Road 5# in Jiashan, zhejiang
Taizhou Shengxing Chempharm Co.,Ltd
Contact:+86-576-88516600
Address:Yantou Chemical Zone Jiaojiang Taizhou Zhejiang China
Contact:0086 371 65711996
Address:Jalan 4/3, Kawasan Perindustrian Serendah, 48000 Rawang,
Doi:10.1021/ja00753a047
(1971)Doi:10.1055/s-0037-1611694
(2019)Doi:10.1080/00397910500191169
(2005)Doi:10.1039/jr9650004246
(1965)Doi:10.1016/S0040-4039(01)00611-6
(2001)Doi:10.1016/S0960-894X(01)00448-6
(2001)