Inorganic Chemistry p. 2672 - 2675 (1971)
Update date:2022-07-29
Topics:
Stanghellini
Rossetti
Gambino
Cetini
The kinetics of the reactions between Cp2Ni2(CO)2 (Cp = cyclopentadienyl) and mono- and bidentate ligands have been studied. The reaction with monodentate ligands proceeds by an SN2 mechanism, but the reaction with bidentate (acetylenic) ligands appears to be a two-stage mechanism with a reversible, first-order process as rate-determining step. The more probable mechanisms are discussed on the basis of the values of the activation parameters and the steric hindrance of the ligand.
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Doi:10.1002/ardp.19723050103
(1972)Doi:10.1016/j.bmcl.2015.12.102
(2016)Doi:10.1021/ic50032a022
(1965)Doi:10.1016/S0040-4039(01)00684-0
(2001)Doi:10.1021/ja00760a029
(1972)Doi:10.1007/BF01435405
(1996)
